Blaney previously won pole position at Phoenix in 2017 and 2019. Despite that, he has never won at the one-mile Arizona race track.
Denny Hamlin, who will start alongside, has won twice at Phoenix in 2012 and later in 2019.
The qualifying session went without incident. All drivers with the exception of Ricky Stenhouse Jr. set a time, who missed the session due to an engine change.
| Pos. | Driver | Team |
| 1 | Ryan Blaney | Team Penske |
| 2 | Denny Hamlin | Joe Gibbs Racing |
| 3 | William Byron | Hendrick Motorsports |
| 4 | Christopher Bell | Joe Gibbs Racing |
| 5 | Aric Almirola | Stewart-Haas Racing |
| 6 | Chase Briscoe | Stewart-Haas Racing |
| 7 | Kyle Larson | Hendrick Motorsports |
| 8 | Austin Cindric | Team Penske |
| 9 | Alex Bowman | Hendrick Motorsports |
| 10 | Joey Logano | Team Penske |
| 11 | Kyle Busch | Joe Gibbs Racing |
| 12 | Tyler Reddick | Richard Childress Racing |
| 13 | Austin Dillon | Richard Childress Racing |
| 14 | Erik Jones | Petty GMS Motorsports |
| 15 | Kurt Busch | 23XI Racing |
| 16 | Kevin Harvick | Stewart-Haas Racing |
| 17 | Ross Chastain | Trackhouse Racing |
| 18 | Brad Keselowski | RFK Racing |
| 19 | Chase Elliott | Hendrick Motorsports |
| 20 | Martin Truex Jr. | Joe Gibbs Racing |
| 21 | Ty Dillon | Petty GMS Motorsports |
| 22 | Michael McDowell | Front Row Motorsports |
| 23 | Daniel Suarez | Trackhouse Racing |
| 24 | Harrison Burton | Wood Brothers |
| 25 | Cole Custer | Stewart-Haas Racing |
| 26 | Chris Buescher | RFK Racing |
| 27 | Bubba Wallace | 23XI Racing |
| 28 | Justin Haley | Kaulig Racing |
| 29 | AJ Allmendinger | Kaulig Racing |
| 30 | Corey LaJoie | Spire Motorsports |
| 31 | Landon Cassill | Spire Motorsports |
| 32 | Cody Ware | Rick Ware Racing |
| 33 | Todd Gilliland | Front Row Motorsports |
| 34 | BJ McLeod | Live Fast Motorsports |
| 35 | Garrett Smithley | Rick Ware Racing |
| 36 | Ricky Stenhouse Jr. | JTG Daugherty Racing |